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144120-53-6 | Fmoc-Asp-allyl ester

Fmoc-Asp-allyl ester NLT 98%

SKU : MC437113

CAS Number : 144120-53-6

Molecular Formula : C22H21NO6 | Molecular Weight : 395.41

Synonyms : Fmoc-Asp-OAll

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Purity NLT 98%
Storage -20 ± 5 ºC

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Chemical Name Fmoc-Asp-allyl ester
CAS Number 144120-53-6
MDL Number MFCD00190874
Molecular Formula C22H21NO6
Molecular Weight 395.41
Synonyms Fmoc-Asp-OAll
α-Allyl esters are useful tools for the on-resin head-to-tail cyclization of peptides and for the synthesis of side-chain lactam peptides, glyco- and sulfo-peptides, and branched peptides. Allyl esters are cleaved under mild conditions using Pd(0). These conditions are compatible with Fmoc- and Boc-SPPS.
The Asp α-Allyl esters show a somewhat higher propensity for base-catalyzed aspartimide formation than the corresponding β-esters.
Fmoc-Asp-OAll is a versatile educt for synthesizing complex Asp and Asn derivatives, e.g., N-glycosylated Asn building blocks.

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